LPI Solder Mask Touch Up Pen SDS
SAFETY DATA SHEET
LPI Solder Mask Touch Up Pen
Section 1 – IDENTIFICATION of Chemical Product / Company Information
1.1 GHS Product Identifier: LPI Solder Mask Touch Up Pen
Other means of product identification: LPI, LPI-DKG, LPI-LG, LPI-BLU, LPI-RED, LPI-BLKF,
LPI-BLKG, LPI-WF, LPI-WG
Product Type: Liquid
1.2 Relevant identified uses of the substance or mixture and uses advised against
Not applicable
1.3 Supplier’s Details: FLS Discount Supplies & Fred LeVine Services Inc.
1415 Redeker St Des Plaines, IL 60016 USA
FLS Discount Supplies Customer Service: 847-867-5030
Fred LeVine Services Inc. Customer Service: 847-297-4555
1.4 Emergency Liquid Specific (with hours of operation): 1-800-424-9300 24/7 Reference ID# C235
Section 2 – HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture :
HMIS
Health: 1, Slight Hazard, Flammability: 2, Moderate Hazard, Reactivity: 0, Minimal Hazard
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.1200, the preparer, has chosen to provide them. HMIS® ratings are to be used only in conjunction with a fully implemented HMIS® program by workers who have received appropriate HMIS® training. HMIS® is a registered trade and service mark of the NPCA. HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868
2.2 GHS label elements
Hazard pictograms: GHS02
Signal word : Danger
2.3 Other Hazards
Emergency Overview: Breathing high concentrations of product may have narcotic effects. Exposure can be irritating to eyes, prolonged exposure irritant to nose, throat, and lungs. May cause skin irritation and/or dermatitis. Combustible material. May cause allergic skin reaction. Appearance liquid. Odor Not available
OSHA Regulatory Status: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Hazardous Components
Chemical Name ACGIH OSHA
Limestone N/E 15 mg/m3- TWA total 5 mg/m3- TWA
Hydrotreated heavy naphtha, petroleum N/E N/E
Soybean oil, polymer with pentaerythritol and
phthalic anhydride N/E N/E
Titanium dioxide 10 mg/m3- TWA 15 mg/m3- TWA total
Iron oxide 5 mg/m3- TWA 10 mg/m3- TWA
Kaolin 2 mg/m3- TWA 15 mg/m3- TWA total5 mg/m3- TWA
Carbon black 3.5 mg/m3- TWA 3.5 mg/m3- TWA
Silica, amorphous N/E - (80)/(% SiO2) mg/m3TWA 20 mppcf - TWA
Aluminum hydroxide 1 mg/m3- TWA N/E
Cobalt bis(2-ethylhexanoate) N/E N/E
Methyl ethyl ketoxime N/E N/E
Ethyl benzene 20 ppm - TWA 100 ppm – TWA 435 mg/m 3- TWA
Silica, crystalline 0.025 mg/m3- TWA respirable - (10)/(%SiO2 + 2) mg/m3 TWA
respirable - (250)/(%SiO2 + 5) mppcf TWA
total dust - (30)/(%SiO2 + 2) mg/m 3 TWA
Legend
ACGIH - American Conference of Governmental Industrial Hygienists Exposure Limits
OSHA - Occupational Safety & Health Administration Exposure Limits
N/E - Not Established
Section 3 - Composition / Information On Ingredients
Chemical Name CAS Number Weight % (max)
Limestone 1317-65-3 35
Hydrotreated heavy naphtha,petroleum 64742-48-9 35
Soybean oil, polymer with
pentaerythritol and phthalic anhydride 66070-60-8 30
Titanium dioxide 13463-67-7 25
Iron oxide 1309-37-1 10
Kaolin 1332-58-7 5
Carbon black 1333-86-4 5
Silica, amorphous 7631-86-9 5
Aluminum hydroxide 21645-51-2 5
Cobalt bis(2-ethylhexanoate) 136-52-7 0.5
Methyl ethyl ketoxime 96-29-7 0.5
Ethyl benzene 100-41-4 0.5
Silica, crystalline 14808-60-7 0.5
Section 4 - First Aid Measures
4.1 Description of first aid measures
Following Eye Contact: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician.
Following Skin Contact: Remove contaminated clothing and wash skin with soap and water. Get medical attention if irritation develops or persists. Wash clothing separately before reuse.
Following Ingestion: If swallowed, give two or more glasses of water immediately. DO NOT induce vomiting. Get medical attention.
Following High Volumes of Inhalation: In case of exposure to high concentrations of vapor or mist, remove to fresh air. If
breathing is difficult, give oxygen and call a Physician. If breathing has stopped, apply artificial respiration and call a Physician.
4.2 Most important symptoms and effects, both acute and delayed
Potential Health Effects
Eyes: Contact with eyes may cause irritation.
Skin: May cause skin irritation and/or dermatitis. May cause allergic skin reaction.
Ingestion: Harmful if swallowed. Ingestion may cause irritation to mucous membranes.
Inhalation: Amount in pen is not dangerous, although high concentrations of vapor may cause headache, dizziness, nausea, vomiting and unconsciousness.
Pre-Existing Medical Conditions Aggravated by Exposure: Lung, eye, skin.
Aggravated Medical Conditions: None known
4.3 Indication of any immediate medical attention and special treatment needed
Notes To Physician: Treat symptomatically
Section 5 - Fire Fighting Measures
5.1 Extinguishing media
Suitable Extinguishing Media: Foam, dry powder or water. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
5.2 Special hazards arising from the substance or mixture
Specific Hazards Arising From The Chemical: Combustible material. Closed containers may rupture if exposed to fire or extreme heat. Keep product and empty container away from heat and sources of ignition. Thermal decomposition can lead to release of irritating gases and vapors.
5.3 Protective Equipment And Precautions For Firefighters:
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
Sensitivity To Mechanical Impact: No
Sensitivity To Static Discharge: Yes
Flash Point Data
Flash Point (°F) 119.0
Flash Point (°C) 48.3
Flash Point Method PMCC
Flammability Limits In Air
Lower Explosion Limit 0.7
Upper Explosion Limit 5.3
NFPA Health: 1, Slightly Flammability: 2, Moderate Instability: 0, Not Hazardous
The ratings assigned are only suggested ratings, the contractor/employer has ultimate responsibilities for NFPA ratings where this system is used. Additional information regarding the NFPA rating system is available from the National Fire Protection Agency (NFPA) at www.nfpa.org
Section 6 - Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedure
Personal Precautions: Use personal protective equipment. Remove all sources of ignition.
6.2 Environmental precautions
Environmental Precautions: Prevent further leakage or spillage if safe to do so. Do not allow material tocontaminate ground water system. Prevent product from entering drains. Do not flushinto surface water or sanitary sewer system. Local authorities should be advised ifsignificant spillages cannot be contained.
6.3 Methods For Clean-Up
Dam up. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. Clean contaminated surface thoroughly.
6.4 Other Information: None known
Section 7 - Handling And Storage
7.1Precautions for safe handling
Protective measures: Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container
Handling : Use only in area provided with appropriate exhaust ventilation. Do not breathevapors or spray mist. Wear personal protective equipment. Take precautionary measures against static discharges. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Keep away from open flames, hot surfaces and sources of ignition.
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas.
7.2 Conditions for safe storage, including any incompatibilities
Storage: Put on appropriate personal protective equipment. Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat. Keep in properly labeled containers. Store in plastic zip seal bags facing pen tip up.
7.3 Specific end uses
DANGER - Rags, steel wool or waste soaked with this product may spontaneously catch fire if improperly discarded. Immediately after use, place rags, steel wool or waste in a sealed water-filled metal container.KEEP OUT OF REACH OF CHILDREN.
Section 8 - Exposure Controls / Personal Protection
Preventive industrial medical examinations are to be carried out.
Section 8. Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient name Exposure limits
|
Propyl acetate
ACGIH TLV (United States, 4/2014) STEL: 1040 mg/m³ 15 minutes. STEL: 250 ppm 15 minutes. TWA: 835 mg/m³ 8 hours. TWA: 200 ppm 8 hours.
NIOSH REL (United States, 10/2013). STEL: 1050 mg/m³ 15 minutes. STEL: 250 ppm 15 minutes. TWA: 840 mg/m³ 10 hours. TWA: 200 ppm 10 hours.
OSHA PEL 1989 (United States, 3/1989). STEL: 1050 mg/m³ 15 minutes. STEL: 250 ppm 15 minutes. TWA: 840 mg/m³ 8 hours. TWA: 200 ppm 8 hours.
OSHA PEL (United States, 2/2013). TWA: 840 mg/m³ 8 hours. TWA: 200 ppm 8 hours. |
2-Butanone
ACGIH TLV (United States, 4/2014). STEL: 885 mg/m³ 15 minutes. STEL:300 ppm 15 minutes. TWA: 590 mg/m³ 8 hours. TWA: 200 ppm 8 hours.
NIOSH REL (United States, 10/2013). STEL: 885 mg/m³ 15 minutes. STEL: 300 ppm 15 minutes. TWA: 590 mg/m³ 10 hours. TWA: 200 ppm 10 hours.
OSHA PEL (United States, 2/2013). TWA: 590 mg/m³ 8 hours. TWA: 200 ppm 8 hours. OSHA PEL 1989 (United States, 3/1989). STEL: 885 mg/m³ 15 minutes. STEL: 300 ppm 15 minutes. TWA: 590 mg/m³ 8 hours. TWA: 200 ppm 8 hours.
|
8.2 Exposure[A1] controls
Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment.
Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures
Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Personal Protective Equipment
Eye/Face Protection Safety glasses with side-shields. If splashes are likely to occur, wear. Tightly fitting safety goggles.
Skin Protection Protective gloves.
Respiratory Protection In operations where exposure limits are exceeded, use a NIOSH approved respiratorthat has been selected by a technically qualified person for the specific work conditions. When spraying the product or applying in confined areas, wear a NIOSHapproved respirator specified for paint spray or organic vapors.
Hygiene Measures Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing before re-use. Wash thoroughly after handling. When using do not eat, drink or smoke.
Section 9 - Physical And Chemical Properties
9.1 Appearance: liquid Odor: Not available
Density (lbs/gal) 9.4 - 11.9 Specific Gravity 1.12 - 1.43
pH Not available Viscosity (centistokes) Not available Evaporation Rate Not available
Vapor Pressure Not available Vapor Density Not available Wt. % Solids 60 – 80 Vol. % Solids 40 - 60
Wt. % Volatiles 20 – 40 Vol. % Volatiles 40 – 60 VOC Regulatory Limit (g/L)< 380
Boiling Point (°F) 365.0 Boiling Point (°C) 185.0
Freezing Point (°F) Not available Freezing Point (°C) Not available
Flash Point (°F) 119.0 Flash Point (°C) 48.3 Flash Point Method PMCC
Upper Explosion Limit 5.3 Lower Explosion Limit 0.7
Chemical Name CAS Number Weight % (max)
Limestone 1317-65-3 35
Hydrotreated heavy naphtha,petroleum 64742-48-9 35
Soybean oil, polymer with
pentaerythritol and phthalic anhydride 66070-60-8 30
Titanium dioxide 13463-67-7 25
Iron oxide 1309-37-1 10
Kaolin 1332-58-7 5
Carbon black 1333-86-4 5
Silica, amorphous 7631-86-9 5
Aluminum hydroxide 21645-51-2 5
Cobalt bis(2-ethylhexanoate) 136-52-7 0.5
Methyl ethyl ketoxime 96-29-7 0.5
Ethyl benzene 100-41-4 0.5
Silica, crystalline 14808-60-7 0.5
Section 10 - Stability And Reactivity
Stability: Stable under normal conditions. Hazardous polymerization does not occur.
Conditions to Avoid: Avoid heat, sparks, open flame and static electricity
Incompatibility: Incompatible with strong acids and bases and strong oxidizing agents.
Hazardous Decomposition: Thermal decomposition can lead to release of irritating gases and vapors.
Hazardous Polymerization: Will not occur under normal conditions.
Conditions to avoid: NA
Section 11 - Toxicological Information
Acute Toxicity
Product
Repeated or prolonged exposure to organic solvents may lead to permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling vapors may be harmful or fatal.
Component
Limestone LD50 Oral: 6,450 mg/kg (Rat) vendor data Sensitization: No sensitizing effects known.
Hydrotreated heavy naphtha, petroleum LD50 Oral: > 5,000 mg/kg (Rat) vendor data LD50 Dermal: > 3,160 mg/kg (Rabbit)
Titanium dioxide LD50 Oral: > 10000 mg/kg (Rat) LD50 Dermal: > 10000 mg/m³ (Rabbit) LC50 Inhalation (Dust): > 6.82 mg/L (Rat, 4 hr.)
Iron oxide LD50 Oral: > 5000 mg/kg (Rat) vendor data
Kaolin LD50 Oral: > 5000 mg/kg (Rat)
Carbon black LD50 Oral: > 15400 mg/kg (Rat), LD50 Dermal: > 3000 mg/kg (Rabbit)
Silica, amorphous LD50 Oral: > 5000 mg/kg (Rat), LD50 Dermal: 2,000 mg/kg (Rabbit), LC50 Inhalation (Dust): > 2 mg/L
Methyl ethyl ketoxime LD50 Oral: 930 mg/kg (Rat), LD50 Dermal: 200 μL/kg (Rabbit), LC50 Inhalation (Vapor): > 4.8 mg/L (Rat)
Ethyl benzene LD50 Oral: 3500 mg/kg (Rat), LD50 Dermal: > 5000 mg/kg (Rabbit), LC50 Inhalation (Vapor): 55000 mg/m3 (Rat, 2 hr.), Sensitization: No sensitizing effects known
Silica, crystalline LD50 Oral: 500 mg/kg (Rat) vendor data
Chronic Toxicity
Carcinogenicity
The information below indicates whether each agency has listed any ingredient as a carcinogen:
Chemical Name ACGIH IARC NTP OSHA
Titanium dioxide 2B – Possible Listed
Human Carcinogen
Carbon black 2B – Possible Listed
Human Carcinogen
Cobalt bis(2-ethylhexanoate) 2B – Possible
Human Carcinogen
Ethyl benzene A3 – Confirmed Animal 2B – Possible Human Carcinogen Listed
Carcinogen with Unknown
Relevance to Humans
Silica, crystalline A2 – Suspected Human 1 – Human Carcinogen Known Human Listed
Carcinogen Carcinogen
Crystalline Silica has been determined to be carcinogenic to humans by IARC (1) when in respirable form. Risk of cancer depends on duration and level of inhalation exposure to spray mist or dust from sanding the dried paint.
• Although IARC has classified titanium dioxide as possibly carcinogenic to humans (2B), their summary concludes: "No significant exposure to titanium dioxide is thought to occur during the use of products in which titanium dioxide is bound to other materials, such as paint."
• Cobalt and cobalt compounds are listed as possible human carcinogens by IARC (2B). However, there is inadequate evidence of the carcinogenicity of cobalt and cobalt compounds in humans.
Legend
ACGIH - American Conference of Governmental Industrial Hygienists
IARC - International Agency for Research on Cancer
NTP - National Toxicity Program
OSHA - Occupational Safety & Health Administration
Section 12 - Ecological Information
Environmental Impact Information
Avoid runoff into storm sewers and ditches which lead to waterways. Water runoff can cause environmental damage.
REPORTING
US regulations require reporting spills of this material that could reach any surface waters. The toll free number for the US Coast Guard National Response Center is: 1-800-424-8802
Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance to local, state and federal regulations and ordinances. Do not allow to enter storm drains or sewer systems.
Section 14 - Transportation Information
Domestic (USDOT) International (IMDG) Air (IATA)
Proper Shipping Name: Paint Paint Paint
Hazard Class: N.A 3 3
UN Number: N.A. UN1263 UN1263
Packing Group: N.A. III III
Limited Quantity: No IMDG 34-08, 3.4.7 Yes
Section 15 - Regulatory Information
U.S. Federal regulations :
TSCA 8(a) PAIR: 2-methoxy-1-methylethyl acetate TSCA 8(a) CDR Exempt/Partial exemption: Not determined All components are listed or exempted.
Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) : Not listed
Clean Air Act Section 602 Class I Substances : Not listed
Clean Air Act Section 602 Class II Substances : Not listed
DEA List I Chemicals (Precursor Chemicals) : Not listed
DEA List II Chemicals (Essential Chemicals) : Listed
SARA 302/ 304 Composition/information on ingredients
No products were found.
SARA 304 RQ : Not applicable.
SARA 311/312 Classification : Fire hazard
Immediate (acute) health hazard
Name % Fire hazard Sudden release Reactive Immediate (acute) Delayed (chronic)
of pressure health hazard health hazard
Propyl acetate 5 - 10 Yes. No. No. Yes. No. 2-Butanone 5 - 15 Yes. No. No. Yes. No.
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA "Hazard Categories" promulgated under Sections 311and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD, FIRE HAZARD
SARA Section 313:
Listed below are the substances (if any) contained in this product that are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS Number
None
Toxic Substances Control Act:
Listed below are substances (if any) contained in product that are subject to reporting requirements of TSCA 12(B) if exported from the USA:
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product.
Chemical Name CAS Number
Limestone 1317-65-3
Alkyd Resin PROPRIETARY
Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%.
Chemical Name CAS Number
Limestone 1317-65-3
Alkyd Resin PROPRIETARY
International Regulations: As follows -
CANADIAN WHMIS: This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
CANADIAN WHMIS CLASS: B3 D2A D2B
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists National inventory Australia :
All components are listed or exempted.
Canada : All components are listed or exempted.
China : All components are listed or exempted.
Europe : All components are listed or exempted.
Japan : All components are listed or exempted.
Republic of Korea : All components are listed or exempted.
Malaysia : All components are listed or exempted.
New Zealand : All components are listed or exempted.
Philippines : All components are listed or exempted.
Taiwan : All components are listed or exempted.
Section 16 - Other Information
VOLATILE ORGANIC COMPOUNDS, g/L: 410
REASON FOR REVISION: Regulatory Update
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Key to abbreviations :
ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations
FLS Discount Supplies & Fred LeVine Services Inc. believes, to the best of its knowledge, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. FLS Discount Supplies & Fred LeVine Services Inc. makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.
Revision Date: 1/28/2019
FLS Discount Supplies SDS # LPI
FLS Discount Supplies
www.pcbsupplies.com
[A1] The information required in the present subsection shall be provided, unless an ES containing that information is attached to the SDS.
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